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She won the Best Actress award at the African Movie Academy Awards 2010 for her role in “The Perfect Picture". A native of Teshie in Accra, Naa was born on November 24 1988 to Mr Paul Mensah-Doku and Sarah Mensah-Doku, the second of four sisters. She attended the Daras School from nursery to JSS and continued at the Benkum Secondary School in Larteh.
Nisirine Naa Ashorkor Mensah-Doku went into presenting when she was invited on several occasions as a guest on a Youth program "New Generation", on TV Africa. She later presented “Day Break Entertainment". She went to host "Day Break" and became a co-host to Okyeame Quophi on TV Africa a variety show “Sounds Splash".
She is now working permanently with an events and production company Charter House, organizes of Ghana Music Awards, as a TV presenter and producer.
Talking about how she ended up in movies, Naa said she accompanied a friend to an auditioning session but ended up being auditioned herself and being picked for consideration.